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Creators/Authors contains: "Albert, Julie"

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  1. Abstract AimsThe goal of this study was to explore the suitability of recycled glass sand for the growth of beach-adapted plant species given the potential environmental benefits of utilizing glass sand for beach and dune restoration in the face of dwindling natural sand resources. MethodsWe grew three species native to US Gulf of Mexico beaches (Ipomoea imperati(Vahl) Griseb.,I. pes-caprae(L.) R.Br., andUniola paniculata(L.)) in three greenhouse experiments in glass sand, beach sand, or mixtures. First, we investigated nutrient and microbial effects by growing each species in pure glass sand, beach sand, and 80%/20% mixtures of glass sand/beach sand. Second, we comparedU. paniculatagrowth in glass sand mixed with 100%, 75%, 50%, 25%, or 0% beach sand. These experiments included fertilizer and microbial sterilization treatments. Third, we investigated soil permeability effects by comparing growth of all species using different grain sizes of glass sand. ResultsOverall, plants produced significantly more biomass in beach sand than in glass sand, and the effect was more pronounced with the fertilizer treatment. There were significant effects of substrate mixtures and interactions with fertilizer treatments onUniolabiomass. Further, when glass sand grain sizes were manipulated, plant biomass was equal or higher in the coarsest glass sand compared to beach sand. ConclusionsOur results demonstrate that beach-adapted plants can grow in glass sand and suggest that recycled glass sand is a potential resource for ecological restoration with incorporation of soil amendments such as fertilizer and utilization of selected grain sizes. 
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  2. ABSTRACT Ternary block copolymer (BCP)‐homopolymer (HP) blends offer a simple method for tuning nanostructure sizes to meet application‐specific demands. Comprehensive dissipative particle dynamic (DPD) simulations were performed to study the impact of polymer interactions, molecular weight, and HP volume fraction (φHP) on symmetric ternary blend morphological stability and domain spacing. DPD reproduces key features of the experimental phase diagram, including lamellar domain swelling with increasingφHP, the formation of an asymmetric bicontinuous microemulsion at a critical HP concentration , and macrophase separation with further HP addition. Simulation results matched experimental values for and lamellar swelling as a function of HP to BCP chain length ratio,α = NHP/NBCP. Structural analysis of blends with fixedφHPbut varyingαconfirmed that ternary blends follow the wet/dry brush model of domain swelling with the miscibility of HPs and BCPs depending onα. Longer HPs concentrate in the center of domains, boosting their swelling efficiencies compared to shorter chains. These results advance our understanding of BCP‐HP blend phase behavior and demonstrate the value of DPD for studying polymeric blends. © 2019 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys.2019,57, 794–803 
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